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He's actually wearing a hairstyle that's only available via Stylist and is hidden in CAS. There are several other hairstyles from Ambitions that act the same way.
You can access this hair several ways:
By changing your sim appearance via a Stylist station.
Or you could use
Nraas Mastercontroller Stylist option.
Or to access this hair in CAS, you can use a cheat:
unlockoutfits on
Or for the same effect as the cheat, you can aslo use
Nraas Mastercontroller (and Integration module) to unlock hidden parts:
City hall or computer > Nraas > Nraas Mastercontroller > Settings > CAS > Category changes > Show hidden parts.
Or edit the CASP to make this hair available in CAS.